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61.
Timo J. Tolmunen Antti V. Räisänen 《International Journal of Infrared and Millimeter Waves》1989,10(4):505-518
The multiplication efficiency of a millimeter-wave Schottky-varactor quintupler with fixed idler terminations was studied. The highest efficiency measured was 4.2% at 168 GHz with 10 mW input power and 3.3% with 40 mW input power. Over the range from 165 GHz to 170 GHz the output power was 0.7–1.3 mW withp
in
=40 mW. 相似文献
62.
Timo Hanke 《Israel Journal of Mathematics》2005,150(1):199-203
The striking results on noncrossed products were their existence (Amitsur [1]) and the determination of ℚ(t) and ℚ((t)) as their smallest possible centres (Brussel [3]). This paper gives the first fully explicit noncrossed product example
over ℚ((t)). As a consequence, the use of deep number theoretic theorems (local-global principles such as the Hasse norm theorem and
density theorems) in order to prove existence is eliminated. Instead, the example can be verified by direct calculations.
The noncrossed product proof is short and elementary.
Supported in part by the DAAD (Kennziffer D/02/00701). 相似文献
63.
64.
Michael Kahnert Timo Nousiainen 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,100(1-3):173-178
The error caused by the uncertainty in the refractive index in the determination of the asymmetry parameter g is studied for a variety of mineral dust aerosol samples at two different optical wavelengths. Lorenz–Mie computations for spherical model particles are compared with results based on laboratory-measured phase functions in conjunction with a commonly used extrapolation method. The difference between the g-value based on measurements and the g-value based on Lorenz–Mie simulations is generally on the same order of magnitude as the error caused by the uncertainty in the refractive index m. For larger effective radii the error in g related to the use of spherical model particles is even larger than that related to the uncertainty in m. This indicates that the use of spherical model particles can be among the major error sources in the determination of the asymmetry parameter of dust aerosols. 相似文献
65.
Tanja Seraidaris Arto Puranen Mikko Karesoja Barbro Lfgren Timo Repo Markku Leskel Jukka Seppl 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4743-4751
Elastic polypropene has gained growing industrial and academic interest as a thermoplastic elastomer. In this study, “rac”‐ and “meso”‐dimethylsilyl(3‐benzylindenyl)(2‐methylindenyl)hafnium dichloride complexes (Hfr and Hfm, respectively), activated with [NHMe2Ph][B(C6F5)4]/triisobutyl aluminum, were used in propene polymerization. Using these catalyst systems, we obtained polymers with high molar masses, up to 550 kg/mol, and moderate isotacticities between 34 and 52%. By varying the polymerization conditions, we could modify the polymer microstructure and molar mass. 13C NMR was used to calculate the polymer pentad sequence distributions. The crystalline parts of the polymers were analyzed with the differential scanning calorimetry successive self‐nucleation and annealing (SSA) technique. The SSA thermograms revealed that Hfr produced polypropene with a more uniform lamellar structure than Hfm. The mechanical properties were tested with dynamic mechanical analysis creep‐recovery tests. In the series, the polymers with the lowest isotacticities and therefore lowest crystallinities showed the best elastic properties. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4743–4751, 2006 相似文献
66.
Summary. In this work we address the issue of integrating
symmetric Riccati and Lyapunov matrix differential equations. In
many cases -- typical in applications -- the solutions are positive
definite matrices. Our goal is to study when and how this property
is maintained for a numerically computed solution.
There are two classes of solution methods: direct and
indirect algorithms. The first class consists of the schemes
resulting from direct discretization of the equations. The second
class consists of algorithms which recover the solution by
exploiting some special formulae that these solutions are known to
satisfy.
We show first that using a direct algorithm -- a one-step scheme or
a strictly stable multistep scheme (explicit or implicit) -- limits
the order of the numerical method to one if we want to guarantee
that the computed solution stays positive definite. Then we show two
ways to obtain positive definite higher order approximations by
using indirect algorithms. The first is to apply a symplectic
integrator to an associated Hamiltonian system. The other uses
stepwise linearization.
Received April 21, 1993 相似文献
67.
Olga Bori Timo J. Tolmunen Erik Kollberg Margaret A. Frerking 《International Journal of Infrared and Millimeter Waves》1992,13(6):799-814
The S-parameters of several different quantum well double barrier diodes have been measured. A technique has been developed for measuring whisker contacted diodes with and HP 8510B automatic network analyzer. Special coaxial mounts using K-connectors were designed to enable measurements up to 20 GHz. The voltage-dependent conductance and capacitance were derived from the measured reflection coefficient of each device. The C/V characteristics were observed to exhibit an anomalous increase at voltages corresponding the the negative differential resistance region (NDR). These are the first reported S-parameter measurements in the negative differential resistance region of quantum well double barrier diodes. A theory is presented that explains, in part, the observed results. 相似文献
68.
Data Envelopment Analysis (DEA) offers a piece-wise linear approximation of the production frontier. The approximation tends to be poor if the true frontier is not concave, eg in case of economies of scale or of specialisation. To improve the flexibility of the DEA frontier and to gain in empirical fit, we propose to extend DEA towards a more general piece-wise quadratic approximation, called Quadratic Data Envelopment Analysis (QDEA). We show that QDEA gives statistically consistent estimates for all production frontiers with bounded Hessian eigenvalues. Our Monte-Carlo simulations suggest that QDEA can substantially improve efficiency estimation in finite samples relative to standard DEA models. 相似文献
69.
Kütt A Movchun V Rodima T Dansauer T Rusanov EB Leito I Kaljurand I Koppel J Pihl V Koppel I Ovsjannikov G Toom L Mishima M Medebielle M Lork E Röschenthaler GV Koppel IA Kolomeitsev AA 《The Journal of organic chemistry》2008,73(7):2607-2620
A general route to functionalized pentakis(trifluoromethyl)phenyl (C6(CF3)5) derivatives, promising building blocks for designing novel stable carbenes, radical species, superacids, weakly coordinating anions and other practically and theoretically useful species, is presented. This pertrifluoromethylation route proceeds via conveniently pregenerated (trifluoromethyl)copper (CF3Cu) species in DMF, stabilized by addition of 1,3-dimethyl-2-imidazolidinone (DMI). These species react with hexaiodobenzene at ambient temperature to give the potassium pentakis(trifluoromethyl)phenoxide along with hexakis(trifluoromethyl)benzene and pentakis(trifluoromethyl)benzene in a combined yield of 80%. A possible reaction pathway explaining the formation of pentakis(trifluoromethyl)phenoxide is proposed. Pentakis(trifluoromethyl)phenol gives rise to easily functionalized pentakis(trifluoromethyl)chlorobenzene and pentakis(trifluoromethyl)aniline. Pertrifluoromethylation of pentaiodochlorobenzene and pentaiodotoluene allows straightforward access to pentakis(trifluoromethyl)chlorobenzene and pentakis(trifluoromethyl)toluene, respectively. XRD structures of several C6(CF3)5 derivatives were determined and compared with the calculated structures. Due to the steric crowding the aromatic rings in all C6(CF3)5 derivatives are significantly distorted. The gas-phase acidities (Delta Gacid) and pKa values in different solvents (acetonitrile (AN), DMSO, water) for the title compounds and a number of related compounds have been measured. The origin of the acidifying effect of the C6(CF3)5 group has been explored using the isodesmic reactions approach. 相似文献
70.
Calcium carbonate (vaterite) nanoparticles of 20-60 nm size were obtained without stabilizing tensides by heating a dispersion of calcium bicarbonate (CaHCO(3)) in ethylene glycol for 30 minutes at 40 to 100 °C. 相似文献